Yw. Chen et Fl. Xiao, COUPLING PHASES AND AMPLITUDES OF MINOR CONSTITUENTS WITH TEMPERATUREPERTURBATIONS IN THE LOWER THERMOSPHERE, Annales geophysicae, 12(5), 1994, pp. 438-447
Based on the linearized theory of atmospheric gravity waves (AGW) and
considering the effects of temperature perturbation on the chemical ra
te coefficients, the formulae of coupling relations between n'(j)/n(j)
and T'/T driven by AGW (n(j) and T denote the background quantities)
are described, the coupling phases and amplitudes of minor constituent
s O3, NO, H, OH, and O are analyzed in detail for the mesopause (86km)
and just upside of the O layer (100km) at daytime. A general principl
e is outlined: the coupling phases are strongly dependent on density s
cale heights and perturbation scales, while the amplitudes are little
affected by these two factors. A criterion to distinguish the coupling
behavior is given: when the minor constituent number density scale he
ight H(j) satisfies 1 - gammaH(m)/H(j) > 0, (H(m) denotes the scale he
ight of the major constituent) the dynamical perturbation process alwa
ys keeps the n'(j)/n(j) in phase with T'/T, i.e. keeps the n'(n)/n(j)
in antiphase with that of the major constituent. The results obtained
indicate that both the temperature dependence of reaction rate coeffic
ients and the profile slopes of the O distribution may have a major in
fluence on the behavior of the coupling relations.