Films of differently modified PVA (polyvinyl alcohol), TA (phthalocyan
inosilicon) and Nafion in different ionic forms (H+, Li+, and Na+) hav
e been prepared by using casting methods. Impedance changes of the fil
ms with relative humidity are examined. The results demonstrate that t
he content and hydrophilicity of the hydrophilic group in PVA, ionizat
ion of TA, and the cation in Nafion have significant effects on sensin
g properties of the films. (C) 1997 Elsevier Science S.A.