O. Gyliene et al., THE USE OF ORGANIC-ACIDS AS PRECIPITANTS FOR METAL RECOVERY FROM GALVANIC SOLUTIONS, Journal of chemical technology and biotechnology, 70(1), 1997, pp. 111-115
The abundance of metal ions in galvanic waste solutions enables these
solutions to be used for recovery of metals as well as complexing agen
ts such as citrate and tartrate. The addition of oxalic acid to soluti
ons containing complexing agents precipitates pure metal oxalate or mi
xtures of metal oxalate and tartrate or citrate, the product depending
on pH and concentration of components. The addition of oxalic acid to
the rinsing bath after electroplating precipitates the most of the me
tals such as Cu(II), Zn(II) and Pb(II).