SYNTHESIS AND CRYSTAL-STRUCTURE OF [P(C6H5)(4)][2,9-(N,N'-(2-NH-(C5H4N)))B10H8]

Authors
NACHTIGAL C PREETZ W
Citation
C. Nachtigal et W. Preetz, SYNTHESIS AND CRYSTAL-STRUCTURE OF [P(C6H5)(4)][2,9-(N,N'-(2-NH-(C5H4N)))B10H8], Zeitschrift fur anorganische und allgemeine Chemie, 623(9), 1997, pp. 1489-1491
Citations number
12
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Zeitschrift fur anorganische und allgemeine Chemie
ISSN journal
00442313 → ACNP
Volume
623
Issue
9
Year of publication
1997
Pages
1489 - 1491
Database
ISI
SICI code
0044-2313(1997)623:9<1489:SACO[>2.0.ZU;2-F
Abstract
[N(C4H9)(4)](2)[B10H10] reacts with 2-aminopyridine forming a product mixture from which [2,9-(N,N'-(2-NH-(C5H4N))]B10H8](-) can be isolated by ion exchange chromatography on diethylaminoethyl(DEAE) cellulose. The crystal structure of [P(C6H5)(4)][2,9-(N,N'(2-NH-(C5H4N))]B10H8] ( triclinic, space group P1, a=10.1103(9), b=11.5665(9), c=14.877(2) Ang strom, alpha=102.600(8), beta=107.567(8) und gamma = 96.487(7)degrees, Z = 2) reveals the bonding of 2-NH2-(C5H4N) via both N atoms to vicin al B atoms of the two square planes of the B-10 cluster (B2-N1=1.541(7 ) und B9-N2=1.505(7) Angstrom) forming a five-membered ring.