SINGLE-STEP FIRST SYNTHESIS OF A 3,6-DIHYDRO-1,2-DITHIIN FROM ITS PARENT 1,4-DITHIOKETONE VIA A STEREOSPECIFIC REARRANGEMENT

Authors
SALAMA P POIRIER M
Citation
P. Salama et M. Poirier, SINGLE-STEP FIRST SYNTHESIS OF A 3,6-DIHYDRO-1,2-DITHIIN FROM ITS PARENT 1,4-DITHIOKETONE VIA A STEREOSPECIFIC REARRANGEMENT, Tetrahedron : asymmetry, 8(16), 1997, pp. 2757-2760
Citations number
15
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear","Chemistry Physical
Journal title
Tetrahedron : asymmetry → ACNP
ISSN journal
09574166
Volume
8
Issue
16
Year of publication
1997
Pages
2757 - 2760
Database
ISI
SICI code
0957-4166(1997)8:16<2757:SFSOA3>2.0.ZU;2-#
Abstract
The one step conversion of bis-thiocamphor into its corresponding 3,6- dihydro-1,2-dithiin was performed via a stereospecific rearrangement. Proof of the reaction stereospecificity was established by full charac terization of the final product. Some speculative mechanistic avenues are exposed. (C) 1997 Elsevier Science Ltd.