PREPARATION AND CRYSTAL-STRUCTURES OF 2 FORMS OF TRANS[CUCL2(N(H)SPH2)(2)] - AN UNUSUAL EXAMPLE OF SQUARE PLANAR PSEUDO-TETRAHEDRAL ISOMERISM IN A NEUTRAL COPPER(II) COMPLEX/

Authors
KELLY PF SLAWIN AMZ WARING KW
Citation
Pf. Kelly et al., PREPARATION AND CRYSTAL-STRUCTURES OF 2 FORMS OF TRANS[CUCL2(N(H)SPH2)(2)] - AN UNUSUAL EXAMPLE OF SQUARE PLANAR PSEUDO-TETRAHEDRAL ISOMERISM IN A NEUTRAL COPPER(II) COMPLEX/, Journal of the Chemical Society. Dalton transactions, (17), 1997, pp. 2853-2854
Citations number
6
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Journal of the Chemical Society. Dalton transactions → ACNP
ISSN journal
03009246
Issue
17
Year of publication
1997
Pages
2853 - 2854
Database
ISI
SICI code
0300-9246(1997):17<2853:PACO2F>2.0.ZU;2-5
Abstract
At ambient temperatures, in acetonitrile, S,S-diphenylsulfimide reacte d with CuCl2 (molar ratio 2:1) to give trans-[CuCl2{N(H)SPh2}(2)]; dep ending upon the crystallisation technique this can be isolated as eith er blue (perfect square-planar geometry) or green (pseudo-tetrahedral) crystals which do not interconvert in the solid state.