K. Franke et al., POLING BEHAVIOR AT THE GRAIN-BOUNDARIES OF FERROELECTRIC PZT THIN-FILMS INVESTIGATED BY ELECTRIC SCANNING FORCE MICROSCOPY, Ferroelectrics. Letters section, 23(1-2), 1997, pp. 1-6
The Electric Scanning Force Microscope is used to investigate the poli
ng behaviour of ferroelectric PZT thin films. Successively measured po
larization distributions were compared with high resolution. The polin
g characteristics are investigated separately at the grain boundaries
and inside the grain volumes. For films prepared by sol-gel processing
, it is shown that the switchable polarization is decreased at the gra
in boundaries with respect to the grain volumes. The coercive field is
clearly increased at the grain boundaries.