M. Neumann et Ke. Geckeler, TELECHELIC POLYMERS WITH AZIDO FUNCTIONS AS REAGENTS FOR 1,3-DIPOLAR CYCLOADDITION REACTIONS, Reactive & functional polymers, 33(2-3), 1997, pp. 173-184
Polymers, poly(oxyethylene)s, bearing chloro- and azido telechelic gro
ups were prepared and characterized by NMR, IR, UV and elemental analy
sis. Using the 1,3-dipolar cycloaddition reaction, Delta 2-triazoline-
norbornane telechelics were obtained. Also, using the azido telechelic
s as precursors, reaction with norbordiene leads to longer polymers wh
ich were characterized by spectroscopic and viscosimetric methods.