THE EFFECT OF POLYMER-SUPPORTED REAGENT STRUCTURE ON THE OXIDATION OFCYCLIC ACETALS

Authors
MASLINSKASOLICH J
Citation
J. Maslinskasolich, THE EFFECT OF POLYMER-SUPPORTED REAGENT STRUCTURE ON THE OXIDATION OFCYCLIC ACETALS, Reactive & functional polymers, 33(2-3), 1997, pp. 247-253
Citations number
11
Categorie Soggetti
Polymer Sciences","Engineering, Chemical","Chemistry Applied
Journal title
Reactive & functional polymers → ACNP
ISSN journal
13815148
Volume
33
Issue
2-3
Year of publication
1997
Pages
247 - 253
Database
ISI
SICI code
1381-5148(1997)33:2-3<247:TEOPRS>2.0.ZU;2-4
Abstract
The bromination of diacetals of terephthalaldehyde and glutaraldehyde by means of polymeric brominating reagents (PBR), poly(N-bromoacrylami de), copoly(N-bromomaleimide(arnide)-limonene and poly(N-bromomethacry lamide) Amberlite IRC-50 Br, was described. The bromination by PBR is more specific than that by 1,3-dibromo-5,5-dimethylhydantoin (DBDMH). The reactivity of -NHBr groups in the oxidation of acetals is consider ably influenced by -COOH groups present in the backbone of PBR.