THE CONFIGURATION EFFECT OF SOME CYCLIC ACETALS ON THE RATE OF OXIDATION BY POLYMERIC COMPLEX OF CO(II)

Authors
MASLINSKASOLICH J MACIONGA A
Citation
J. Maslinskasolich et A. Macionga, THE CONFIGURATION EFFECT OF SOME CYCLIC ACETALS ON THE RATE OF OXIDATION BY POLYMERIC COMPLEX OF CO(II), Reactive & functional polymers, 33(2-3), 1997, pp. 255-261
Citations number
12
Categorie Soggetti
Polymer Sciences","Engineering, Chemical","Chemistry Applied
Journal title
Reactive & functional polymers → ACNP
ISSN journal
13815148
Volume
33
Issue
2-3
Year of publication
1997
Pages
255 - 261
Database
ISI
SICI code
1381-5148(1997)33:2-3<255:TCEOSC>2.0.ZU;2-W
Abstract
Cobalt(II) bound to copolymer of maleic acid and ethyl vinyl ether, cr osslinked with 10 mol% 1,6-hexamethylenediamine was found to catalyze the oxidation of 2-styryl-1,3-dioxane and its alkyl substituted deriva tives as well as 4,5-dimethyl-2-styry1-1,3-dioxolane affording hydroxy -alkyl-cinnamates. The effect of polymeric Co(II) complex on the regio selectivity of the oxidation of 4-methyl-2-styryl-1,3-dioxane and cis- syn 4,5-dimethyl-2-styry1-1,3-dioxolane was observed. A free-radical m echanism is proposed.