The enhancement of dielectronic recombination by applied electric fiel
ds has been observed and measured for the first time in a wide range o
f controlled and measurable fields using multiply charged ions. The he
avy ion storage ring CRYRING at Stockholm University was used to store
a beam of Si11+ and collide it with a cold electron target. Rydberg r
esonances up to n = 25 are resolved for both the 2(p3/2) and 2(p1/2) s
eries. The observation of a substantial monotonic increase of the rate
coefficient for the group of higher Rydberg states is in puzzling dis
agreement with theoretical calculations of electric field enhanced die
lectronic recombination.