E. Moralessanchez et al., DETERMINATION OF THE TEMPERATURE OF GELATINIZATION AND ENERGY OF TRANSFORMATION OF STARCH BY DIELECTRIC DISSIPATION INDUCED CHANGES, Starke, 49(7-8), 1997, pp. 268-272
In this work we present a new method which allows to determine the str
uctural changes of starches subjected to a thermal process. Using that
method, the initial and final gelatinization temperatures and the amo
unt of energy required to induce the thermal changes can be deduced. T
he method takes the advantage of the dielectric dissipation of electri
cal energy in the system consisting of a mixture of starch grains and
water enclosed in a specially designed sealed cell. AC electrical powe
r at a fixed voltage and frequency is applied to the material to be st
udied. The magnitude of the electric current is then monitored as the
temperature is raised (by Joule effect) up to temperatures of 120 degr
ees C. The plots of the electric current Vs temperature in all the sam
ples studied yield two distinct extreme values: the onset and the endi
ng temperatures of the gelatinization of the processed samples. Analyz
ing the current Vs time plots during the gelatinization of starch, we
are able to determine the energy required for the transformation proce
ss. The method as such, demonstrates to be a useful technique to deter
mine the basic parameters during starch gelatinization and it is much
simpler then those known in the field.