MAGNETIC-PROPERTIES OF THE NEW TBFESI2-TYPE NDRHCU0.5SI1.5 AND PRRHCU0.5SI1.5 COMPOUNDS FROM MAGNETIC MEASUREMENTS AND NEUTRON-DIFFRACTION

Citation
Mn. Norlidah et al., MAGNETIC-PROPERTIES OF THE NEW TBFESI2-TYPE NDRHCU0.5SI1.5 AND PRRHCU0.5SI1.5 COMPOUNDS FROM MAGNETIC MEASUREMENTS AND NEUTRON-DIFFRACTION, Journal of alloys and compounds, 257(1-2), 1997, pp. 30-35
Citations number
29
Categorie Soggetti
Chemistry Physical","Metallurgy & Metallurigical Engineering","Material Science
ISSN journal
09258388
Volume
257
Issue
1-2
Year of publication
1997
Pages
30 - 35
Database
ISI
SICI code
0925-8388(1997)257:1-2<30:MOTNTN>2.0.ZU;2-5
Abstract
Crystallographic and magnetic properties of PrRhCu0.5Si1.5 and NdRhCu0 .55Si1.5 have been investigated. Both compounds crystallize in the TbF eSi(2)type structure and display an antiferromagnetic transition at T- N=15 K. Neither of the two display spontaneous magnetization at 4 K. N eutron diffraction patterns reveal simple collinear antiferromagnetic structures with moment values equivalent to 2.39 mu(B) for Nd and 2.19 mu(B) for Pr. The magnetic structures are also described as antiferro magnetic BaAl4 blocks connected by ferromagnetic AIB(2) blocks. The re sults are discussed and compared to the magnetic behavior of RRh2X2 ge rmanides and silicides. (C) 1997 Elsevier Science S.A.