DEHYDROCOUPLING OF SILANES CATALYZED BY ZIRCONOCENE-ALKYNE AND TITANOCENE-ALKYNE COMPLEXES

Authors
PEULECKE N THOMAS D BAUMANN W FISCHER C ROSENTHAL U
Citation
N. Peulecke et al., DEHYDROCOUPLING OF SILANES CATALYZED BY ZIRCONOCENE-ALKYNE AND TITANOCENE-ALKYNE COMPLEXES, Tetrahedron letters, 38(38), 1997, pp. 6655-6656
Citations number
12
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
38
Issue
38
Year of publication
1997
Pages
6655 - 6656
Database
ISI
SICI code
0040-4039(1997)38:38<6655:DOSCBZ>2.0.ZU;2-P
Abstract
The zirconocene-and titanocene alkyne complexes 1-10 were tested to be effective catalysts in the dehydrocoupling of hydrosilanes like PhMeS iH2 and Ph2SiH2 to give oligomers and of other examples, e.g., PhSiH3 polymers with cyclic oligosilanes as byproducts. (C) 1997 Elsevier Sci ence Ltd.