S. Kashimura et al., SYNTHESIS OF SYMMETRICAL AND UNSYMMETRICAL 1,2-DIKETONES THROUGH CATHODIC INTRAMOLECULAR COUPLING OF DIESTERS, Tetrahedron letters, 38(38), 1997, pp. 6717-6720
Electroreduction of diesters [(RCOO)-C-1(CH2)(2)OCOR2] with Mg electro
de has been found to give the corresponding unsymmetrical 1,2-diketone
s ((RCOCOR2)-C-1) with excellent yields. (C) 1997 Elsevier Science Ltd
.