2-MERCAPTO-1-METHYLPYRROLE AND THE ANALOGOUS SELENOL - FORMATION AND SOME TRANSFORMATIONS

Authors
VVEDENSKY VY BRANDSMA L SHTEPHAN ED TROFIMOV BA
Citation
Vy. Vvedensky et al., 2-MERCAPTO-1-METHYLPYRROLE AND THE ANALOGOUS SELENOL - FORMATION AND SOME TRANSFORMATIONS, Tetrahedron, 53(38), 1997, pp. 13079-13084
Citations number
10
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron → ACNP
ISSN journal
00404020
Volume
53
Issue
38
Year of publication
1997
Pages
13079 - 13084
Database
ISI
SICI code
0040-4020(1997)53:38<13079:2ATAS->2.0.ZU;2-#
Abstract
The Previously unknown 2-mercapto-1-methylpyrrole and the analogous se lenol have been generated by aqueous hydrolysis of 1-methyl-2-trimethy lsilylthiopyrrole and the corresponding seleno derivative. The thiol-t hione (or selenol-selenone) tautomery appeared from the formation of d imeric products, the addition of benzenethiol and from NMR-spectroscop ical data. (C) 1997 Elsevier Science Ltd.