BETA-CO-(ET)(2)I-3 - NONELECTROCHEMICAL SYNTHESIS AND STRUCTURAL AND PHYSICAL-PROPERTIES OF ANORGANIC SUPERCONDUCTOR WITH 7.1 ESS-THAN-OR-EQUAL-TO-T-C-LESS-THAN-OR-EQUAL-TO-7.9 K
H. Muller et al., BETA-CO-(ET)(2)I-3 - NONELECTROCHEMICAL SYNTHESIS AND STRUCTURAL AND PHYSICAL-PROPERTIES OF ANORGANIC SUPERCONDUCTOR WITH 7.1 ESS-THAN-OR-EQUAL-TO-T-C-LESS-THAN-OR-EQUAL-TO-7.9 K, Advanced materials, 9(11), 1997, pp. 896
Synthesis of the superconducting radical cation salt beta(CO)-(ET)(2)I
-3 obtained by the direct oxidation of either hydrogenated or deuterat
ed bis(ethylenedithio)tetrathiafulvalene (ET) with a stoichiometric am
ount of iodine is reported. The Structural and physical properties of
the resulting compounds are presented and compared with those of other
(ET)(2)I-3 phases. beta(CO)-(ET)(2)I-3 is found to have very similar
superconducting properties to those of alpha(t)-(ET)(2)I-3 and the que
stion is raised as to whether they are actually distinct phases.