K. Sodeyama et al., PROCESSING AND SOME PROPERTIES OF SHIRASUALUMINA LIGHT WEIGHT COMPOSITES/, Nippon Seramikkusu Kyokai gakujutsu ronbunshi, 105(9), 1997, pp. 815-820
Processing and some properties of 28.6 mass% Shirasu/71.4 mass% alumin
a light weight composites were studied to develop the dielectric const
ant and hermeticity required high performance microelectronic ceramic
substrates. Colloidal processing was applied to obtain homogeneous and
dense compact of Shirasu (or Shirasuballoons) and alumina. Mixed susp
ension of pulverized Shirasu particles (diameter of 8.2 mu m) or Shira
suballoons (15 mu m), and alumina particles (0.5 mu m) were prepared b
y adding an appropriate amount of polyelectrolyte. The green compacts
were sintered at 1300-1500 degrees C for 1h in air. The flexural stren
gth of Shirasu/alumina composites sintered at 1400 degrees C showed ma
ximum value. Relative dielectric constant of the Shirasu/alumina compo
sites was lower than that of the sintered monolithic alumina, which wa
s interpreted by a modified Maxwell's equation. Mullite formation was
confirmed for the Shirasu/alumina composites sintered at 1500 degrees
C by X-ray diffractometer.