An approximate treatment of the three-band Hubbard model is developed
which allows the calculation of spectral functions on the CuO2 Planes
of superconducting cuprates. The lattice is divided into CuO2 Clusters
(trimers), on which the Hamiltonian can be diagonalized. The hole con
centrations on both orbitals and the amplitude of the staggered magnet
ization are obtained as a function of the total number of holes throug
h a linear interpolation of the Green functions. The stoichiometric co
mpound is a charge transfer insulator in the antiferromagnetic phase.
Magnetic order is destroyed at different concentrations for electron a
nd hole doping.