A study of a thermal wave hydrogen sensor interrogated via transverse
optical beam deflection spectroscopy is presented. The sensor is a thi
n film polyvinylidene fluoride film coated with a thin palladium layer
. The sensitivity to hydrogen results from thermal boundary condition
changes at the gas-film interface and depends upon the thermophysical
properties of the gas. A simple one-dimensional model is developed to
qualitatively and semi-quantitatively describe the experimental result
s and it shows good agreement with the experiment. Concentrations of 0
.1% hydrogen in the presence of a balanced air mixture and at room tem
perature were measured for this sensor and they indicate possible sens
itivities approaching 100 ppm. (C) 1997 American Institute of Physics.