Na. Peppas et Dja. Ende, CONTROLLED-RELEASE OF PERFUMES FROM POLYMERS .2. INCORPORATION AND RELEASE OF ESSENTIAL OILS FROM GLASSY-POLYMERS, Journal of applied polymer science, 66(3), 1997, pp. 509-513
Release of essential oils from glassy hydrophilic copolymers of 2-hydr
oxyethylmethacrylate (HEMA) and ethylene glycol dimethacrylate (EGDMA)
was studied in a range of releasing media at 30 degrees C. The releas
e of carvone, limonene, and eugenol was investigated using swelling-co
ntrolled release systems based on these copolymers. By changing the cr
osslinking ratio of the copolymers it was possible to achieve zero-ord
er release. The amount of essential oil release was correlated to the
thermodynamic compatibility of the oil-polymer pair, as judged by the
solubility parameter difference. (C) 1997 John Wiley & Sons, Inc.