MORPHOLOGY OF EXTRUDED HIGH-DENSITY POLYETHYLENE PIPES STUDIED BY ATOMIC-FORCE MICROSCOPY

Atomic force microscopy (AFM) was used to study the structure of extru ded polyethylene (PE) pipe. During extrusion, the outer surface of the pipe was cooled with water. Two cross sections, parallel and transver se to the extrusion direction, were examined in order to spatially fol low the structural development during extrusion. The morphology reveal ed was spherulitic, and the spherulites had a mostly banded appearance when viewed under the AFM. We were not able to distinguish an oriente d skin layer at the surface of the pipe, either by AFM or polarizing m icroscopy. The changes in the pipe's structure resulting from the cool ing conditions were found to be rather gradual, and no clearly defined zones were observed. A slight orientation towards the extrusion direc tion was detected only in the area of the pipe crystallized under the lowest degree of undercooling. Measured spherulitic size, band period, and lamellae thickness showed a gradual increase in their values from the cooled to the noncooled surface of the pipe. Transmission electro n microscopy (TEM) was used to verify the band period and lamellae thi ckness measurements done by AFM. (C) 1997 John Wiley & Sons, Inc.