STEREOSPECIFIC SYNTHESIS OF CONDURAMINE-F4 AND CONDURITOL-F (LEUCANTHEMITOL)

Authors
SECEN H GULTEKIN S SUTBEYAZ Y BALCI M
Citation
H. Secen et al., STEREOSPECIFIC SYNTHESIS OF CONDURAMINE-F4 AND CONDURITOL-F (LEUCANTHEMITOL), Synthetic communications, 24(15), 1994, pp. 2103-2108
Citations number
19
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Synthetic communications → ACNP
ISSN journal
00397911
Volume
24
Issue
15
Year of publication
1994
Pages
2103 - 2108
Database
ISI
SICI code
0039-7911(1994)24:15<2103:SSOCAC>2.0.ZU;2-T
Abstract
Stereospecific synthesis of Conduramine-F4 and Conduritol-F has been a chieved by fully stereospecific cyloaddition of singlet oxygen to cycl ohexadiene ketal 1 followed by reductive extrusion of one oxygen atom. The obtained monoepoxide 3 has been smoothly opened to conduritol-F4 and conduramine-F4 6 by water and ammonia, respectively.