MILD DEPROTECTION OF METHYL, BENZYL, METHOXYMETHYL, METHYLTHIOMETHYL,METHOXYETHOXYMETHYL, AND BETA-(TRIMETHYLSILYL)ETHOXYMETHYL ESTERS WITH ALCL3-N,N-DIMETHYLANILINE

Authors
AKIYAMA T HIROFUJI H HIROSE A OZAKI S
Citation
T. Akiyama et al., MILD DEPROTECTION OF METHYL, BENZYL, METHOXYMETHYL, METHYLTHIOMETHYL,METHOXYETHOXYMETHYL, AND BETA-(TRIMETHYLSILYL)ETHOXYMETHYL ESTERS WITH ALCL3-N,N-DIMETHYLANILINE, Synthetic communications, 24(15), 1994, pp. 2179-2185
Citations number
20
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Synthetic communications → ACNP
ISSN journal
00397911
Volume
24
Issue
15
Year of publication
1994
Pages
2179 - 2185
Database
ISI
SICI code
0039-7911(1994)24:15<2179:MDOMBM>2.0.ZU;2-T
Abstract
Methyl, benzyl, methoxymethyl, methylthiomethyl, methoxyethoxymethyl, and beta-(trimethylsilyl)ethoxymethyl esters could be cleaved readily under mild conditions on treatment with AlCl3-N,N-dimethylaniline in C H2Cl2 to give parent carboxylic acids in high yields.