STRUCTURE AND PHOTOPHYSICS OF DEAZABIPYRIDYLS - EXCITED INTERNALLY HYDROGEN-BONDED SYSTEMS WITH ONE PROTON-TRANSFER REACTION SITE

Authors
KACZMAREK L BALICKI R LIPKOWSKI J BOROWICZ P GRABOWSKA A
Citation
L. Kaczmarek et al., STRUCTURE AND PHOTOPHYSICS OF DEAZABIPYRIDYLS - EXCITED INTERNALLY HYDROGEN-BONDED SYSTEMS WITH ONE PROTON-TRANSFER REACTION SITE, Perkin transactions. 2, (7), 1994, pp. 1603-1610
Citations number
31
Categorie Soggetti
Chemistry Physical","Chemistry Inorganic & Nuclear
Journal title
Perkin transactions. 2 → ACNP
ISSN journal
03009580
Issue
7
Year of publication
1994
Pages
1603 - 1610
Database
ISI
SICI code
0300-9580(1994):7<1603:SAPOD->2.0.ZU;2-9
Abstract
Two deazabipyridyls, 2-(2-hydroxyphenyl)pyridin-3-ol 1 and 2-(2-pyridy l)phenol 2, are the objects of X-ray and spectroscopic studies. Their syntheses, crystal structures and photophysics in comparison with [2,2 '-bipyridyl]-3,3'-diol and [2,2'-bipyridyl]-3-ol 3 are described. The influence of the molecular structure on the efficiency of the proton-t ransfer reaction in the S1 state is discussed. The experimental data a re compared with semiempirical quantum chemical calculations.