FORMATION OF 2-DIMENSIONAL STRUCTURES FROM COLLOIDAL PARTICLES ON FLUORINATED OIL SUBSTRATE

Citation
Gs. Lazarov et al., FORMATION OF 2-DIMENSIONAL STRUCTURES FROM COLLOIDAL PARTICLES ON FLUORINATED OIL SUBSTRATE, Journal of the Chemical Society. Faraday transactions, 90(14), 1994, pp. 2077-2083
Citations number
45
Categorie Soggetti
Chemistry Physical","Physics, Atomic, Molecular & Chemical
ISSN journal
09565000
Volume
90
Issue
14
Year of publication
1994
Pages
2077 - 2083
Database
ISI
SICI code
0956-5000(1994)90:14<2077:FO2SFC>2.0.ZU;2-L
Abstract
We propose a new type of liquid substrate, perfluorinated oil (F-oil), for the formation of two-dimensional arrays from colloidal particles. The appropriate conditions for particle ordering (experimental cell, type and concentration of surfactants, etc.) are reported. Large and w ell ordered structures from mum-sized latex particles are obtained. Or dered clusters of globular protein (ferritin) macromolecules are also observed. The structures formed are directly transferred (after the F- oil evaporation) onto a solid substrate for subsequent study by means of optical and electron microscopy. The mechanism of the ordering proc ess is studied and the advantages and disadvantages of the liquid subs trates (in comparison with the solid ones) are discussed. Some possibl e ways for control of the ordering process and for improvement of the quality of the arrays are pointed out.