Gs. Lazarov et al., FORMATION OF 2-DIMENSIONAL STRUCTURES FROM COLLOIDAL PARTICLES ON FLUORINATED OIL SUBSTRATE, Journal of the Chemical Society. Faraday transactions, 90(14), 1994, pp. 2077-2083
Citations number
45
Categorie Soggetti
Chemistry Physical","Physics, Atomic, Molecular & Chemical
We propose a new type of liquid substrate, perfluorinated oil (F-oil),
for the formation of two-dimensional arrays from colloidal particles.
The appropriate conditions for particle ordering (experimental cell,
type and concentration of surfactants, etc.) are reported. Large and w
ell ordered structures from mum-sized latex particles are obtained. Or
dered clusters of globular protein (ferritin) macromolecules are also
observed. The structures formed are directly transferred (after the F-
oil evaporation) onto a solid substrate for subsequent study by means
of optical and electron microscopy. The mechanism of the ordering proc
ess is studied and the advantages and disadvantages of the liquid subs
trates (in comparison with the solid ones) are discussed. Some possibl
e ways for control of the ordering process and for improvement of the
quality of the arrays are pointed out.