Cm. Huang et al., CARBON-COATED-GLASS-FIBER-REINFORCED CEMENT COMPOSITES .1. FIBER PUSHOUT AND INTERFACIAL PROPERTIES, Journal of the American Ceramic Society, 80(9), 1997, pp. 2326-2332
Interfacial mechanical properties of carbon-coated-S-glass-fiber-reinf
orced cement were characterized by a fiber pushout technique. The push
out experiments were conducted on model composites, where the S-gIass
monofilaments with and without carbon coating were unidirectionally em
bedded in ordinary portland cement. Interfacial properties, including
bonding strength, frictional stress, residual stress, and fracture ene
rgy, were extracted from the previously developed progressive debondin
g model, The composite with a carbon interface exhibited a weaker inte
rfacial bonding strength and frictional stress than did the composite
without a carbon interface, The interfacial fracture energy of the com
posite with a carbon interface was 7.9 J/m(2), as compared to 47.6 J/m
(2) for the composite without a carbon interface. The composite with t
he carbon interface exhibited a smaller residual clamping stress (Is M
Pa), in comparison to that for the composite without a carbon interfac
e (69 MPa). Scanning electron microscopy observations indicated that t
he filament without a carbon coating was significantly attacked by the
alkaline environment and was strongly bonded onto the matrix, whereas
the filament with a carbon coating remained intact under the same cur
ing conditions. These studies suggest that carbon coating provides the
glass fiber with significantly improved corrosion resistance to alkal
i in the cement environment.