De. Dausch, FERROELECTRIC POLARIZATION FATIGUE IN PZT-BASED RAINBOWS AND BULK CERAMICS, Journal of the American Ceramic Society, 80(9), 1997, pp. 2355-2360
The ferroelectric fatigue behavior of high-displacement reduced and in
ternally biased oxide wafer (RAINBOW) actuators was investigated and c
ompared with that of conventional bulk ceramics. Piezoelectric lead zi
rconate titanates (PZT-5H and PZT-5A) as well as electrostrictive lead
lanthanum zirconate titanate (PLZT 9/65/35) materials were studied. P
iezoelectric bulk ceramics experienced a 25% decrease in remanent pola
rization over 10(8) switching cycles, whereas RAINBOW polarization deg
raded by 33%-53%. Bulk ceramic and RAINBOW electrostrictors both fatig
ued only 8%. Bulk ceramics fatigued as a result of reorientation of th
e polar axes away from the electric-field direction, RAINBOW fatigue w
as believed to have been caused by degradation at the interface betwee
n the oxide and chemically reduced layers.