P. Stefanov et A. Stanchev, SURFACE SEGREGATION AND PREFERENTIAL SPUTTERING IN THIN AL-NI ALLOY-FILMS, Materials chemistry and physics, 50(3), 1997, pp. 209-212
The surface composition of AlxNi1-x alloy films was studied by X-ray e
lectron spectroscopy (XPS) after various surface treatments and oxidat
ion at room temperature. Ion etching caused a marked enrichment in Ni
of the altered surface layer. After extensive sputtering, bombardment-
induced segregation of Al at the outermost surface layer of the films
was established. Al segregation to the surface was observed during ann
ealing up to 1200 K. The interaction of oxygen with the surface of the
alloy films caused surface segregation of Al, accompanied by preferen
tial oxidation of Al. (C) 1997 Elsevier Science S.A.