CHIROPTICAL PROPERTIES OF BI25FEO39 CRYSTALS

Citation
Vi. Burkov et al., CHIROPTICAL PROPERTIES OF BI25FEO39 CRYSTALS, Inorganic materials, 33(3), 1997, pp. 310-312
Citations number
11
Categorie Soggetti
Material Science
Journal title
ISSN journal
00201685
Volume
33
Issue
3
Year of publication
1997
Pages
310 - 312
Database
ISI
SICI code
0020-1685(1997)33:3<310:CPOBC>2.0.ZU;2-F
Abstract
The circular dichroism (CD) spectra and the rotatory dispersion of Bi2 5FeO39 crystals grown from a bismuth oxide flux were investigated. The electronic transitions involving d-electrons of the Fe atom in the [F eO4](5-) complex were found to give rise to CD bands of both signs and to provide a negative contribution to the rotatory dispersion of Bi25 FeO39 crystals.