D. Peters et al., OXIDIZED AMORPHOUS-SILICON AS GATE INSULATOR FOR SILICON TIPS, Journal of vacuum science & technology. B, Microelectronics and nanometer structures processing, measurement and phenomena, 12(2), 1994, pp. 652-654
Field emission cathode arrays of Betsui type [K. Betsui, Technical Dig
est of the International Vacuum of Microelectronics Conference, Nagaha
ma, Japan, 1991 (unpublished)] need an intermediate spacer layer with
excellent insulator properties, i.e., ultrahigh resistivity, high brea
kdown voltage, excellent adhesion both to substrate and gate layer, lo
w roughness, low dielectric constant, and sufficient long term stabili
ty. This study reports on an investigation of various fabrication meth
ods for this insulating film in order to optimize its properties. Sili
con and some compounds (a: Si, SiO, SiO2, SiO(x)N(y)) have been deposi
ted by e-beam or thermal evaporation and plasma enhanced chemical vapo
r deposition, respectively. These layers have been annealed or oxidize
d before deposition of the extraction gate layer. The structures have
been characterized by means of capacitance measurements. The best resu
lts have been obtained with the deposition of pure silicon by e-beam e
vaporation followed by an oxidization process. The method described in
detail results in an insulator consisting of SiO2 which exhibits exce
llent insulating properties (breakdown field strength 7 MV/cm). Field
emission cathodes fabricated in this manner exhibit stable emission cu
rrents up to 1 muA/tip.