H. Luo et al., 1ST INDICATIONS OF SPONTANEOUS ORDERING IN ZNSE0.50TE0.50 ALLOY, Journal of vacuum science & technology. B, Microelectronics and nanometer structures processing, measurement and phenomena, 12(2), 1994, pp. 1140-1142
We describe our study of II-VI alloy ZnSe0.5Te0.5 in search of spontan
eous ordering. Samples were prepared by molecular beam epitaxy in a va
riety of structure configurations and growth temperatures, in order to
scan a wide range of parameters and identify a favorable condition fo
r ordering. Transmission electron microscopy was carried out on these
samples and revealed indications of spontaneous ordering in several sa
mples, where regions with stacking of atoms that appear to be differen
t from the zinc-blende structure were observed. Preliminary study show
s that such regions have the CuAu [i.e., the (100) superlattice] struc
ture.