C. Varanasi et al., ND SUBSTITUTION IN Y BA SITES IN MELT-PROCESSED YBA2CU3O7-DELTA THROUGH ND2O3 ADDITIONS/, Journal of electronic materials, 24(12), 1995, pp. 1949-1953
YBa2Cu3O7-delta (Y123) samples with excess Nd2O3 and Y2O3 additions in
the same molar ratios were melt textured in air. In the Nd-doped samp
les, in addition to Y ion site substitution, partial substitution into
the Ba2+ sites is anticipated because of the similar ionic sizes of N
d3+ and Ba2+. The microstructure, T-c, and magnetic properties of Nd-d
oped samples were analyzed and compared with undoped Y123 and samples
with excess Y2O3. The Nd2O3 additions lead to significant magnetizatio
n improvements, likely due to both rare earth- and Ba-site substitutio
n by the doped Nd3+ ions, and to increases in T-c. Y2O3 additions resu
lted in no marked property enhancement.