L. Capodieci et al., NOVEL POSTEXPOSURE BAKE SIMULATOR - FIRST RESULTS, Journal of vacuum science & technology. B, Microelectronics and nanometer structures processing, measurement and phenomena, 13(6), 1995, pp. 2963-2967
We have designed and implemented a simulator that models the physics o
f the chemically amplified photoresist process postexposure bake (FEB)
step, based on a general mathematical formulation. The photoacid loss
due to kinetic reaction and the photoacid diffusion are simulated usi
ng experimentally determined model parameters. The FEB simulator, whic
h can be used in conjunction with any lithographic image modeling soft
ware, has been integrated into the CXrL ToolSet, a comprehensive model
ing system for x-ray lithography. The FEB simulator converts the depos
ited dose into an initial concentration of photoacid, and then compute
s its evolution and the corresponding evolution of the protected sites
, for a given bake time and temperature. System dynamics are defined b
y coupled partial differential equations containing acid loss and diff
usion terms. As the two phenomena take place at the same time during F
EB, the numerical algorithm does not separate the terms in the calcula
tion. An alternating direction implicit and explicit numerical differe
ntiation technique for solving a multidimensional partial differential
equation in x and z has been employed, resulting in a system which re
duces computational complexity without loss of accuracy or speed. Line
width can be extracted from the final profile of the protected sites,
or, alternatively, the concentration of the protected sites can be con
verted into a dissolution rate and fed to other dissolution modeling t
ools to generate a developed resist profile. Process latitude simulati
ons can be performed to study linewidth variation with respect to dose
, gap or focus, bake temperature, and time. An initial evaluation has
been performed by comparing simulation results with data from an x-ray
lithography experimental study. (C) 1995 American Vacuum Society.