Jw. Talor et al., PROCESSING CONTROL FOR 0.25 MU-M X-RAY-EXPOSURES OF COMMERCIALLY AVAILABLE RESISTS - THE POTENTIAL FOR ADAPTIVE-CONTROL, Journal of vacuum science & technology. B, Microelectronics and nanometer structures processing, measurement and phenomena, 13(6), 1995, pp. 3078-3081
The processing of chemically amplified resists to yield 0.25 mu m stru
ctures requires control of a number of key parameters. Some of these m
ay be at the limits of the control range or at the limits of achievabl
e uniformity. Where it may not be possible to improve the control or t
he uniformity, it may be possible to use adaptive control to compensat
e. The focus of this article is to explore what is needed for adaptive
control with two commercial x-ray resists, Shipley SAL 505 (negative
tone) and Hoechst AZ PF-514 (positive tone) and to explore the feasibi
lity of adaptive control with the SAL 605 resist. Statistical optimiza
tion has been used previously to provide robust process latitude by fo
cusing on the preexposure bake temperature and time, the x-ray dose, a
nd the postexposure bake temperature and time. To determine the requir
ed control and the slope of the linewidth change with the change in ea
ch variable, a statistical model of the response surface was construct
ed. The statistical results and new work with developer normality poin
t out the major contributions from the wafer baking conditions using a
track vacuum hot plate. The different slopes of the variations with l
inewidth suggest that whole wafer compensation may be possible for cer
tain parameters, and that field-to-field variation arising from hot pl
ate uniformity might be compensated for the SAL 605 resist with anothe
r Preliminary results with Fourier transform infrared spectroscopy wil
l be presented that support these approaches and suggest that further
efforts to provide in-line measurements might be justified by correlat
ing the infrared cross-linking signal with the processing parameter th
at yields the correct linewidth. (C) 1995 American Vacuum Society.