J. Trube et al., LOW-STRESS AND OPTICALLY TRANSPARENT CHROMIUM-OXIDE LAYER FOR X-RAY MASK MAKING, Journal of vacuum science & technology. B, Microelectronics and nanometer structures processing, measurement and phenomena, 11(6), 1993, pp. 2990-2993
This article describes the properties of dc-sputtered chromium oxide l
ayers such as internal stress, density, growth rate, and microstructur
e. Besides these mechanical properties, the composition of the layers
and the optical properties such as transmissivity and refractive index
were also investigated. Transparent, low-stress, and smooth chromium
oxide layers were obtained by optimizing the sputtering conditions: ga
s pressure, O2 content in the working gas, dc-power density, and annea
ling temperature. The most critical parameter is the O2 content in the
working gas. Using these optimized chromium oxide layers in the mask
fabrication process as a masking, as well as an etch stop layer for th
e W etching, the etching behavior during absorber patterning in a subt
ractive x-ray mask production process was improved.