After extracting free fatty acids (FFA) from a model crude vegetable o
il with methanol, FFA were separated from methanol by nanofiltration.
Of the several commercially available membranes that were evaluated, t
he best resulted in FFA rejection of >90% and flux of >25 Lm(-2) h(-1)
. A combination of high-rejection and low-rejection membranes resulted
in a retentate stream of 35% FFA and a permeate stream with less than
0.04% FFA, which can be recycled to the extractor. No alkali is requi
red, no soapstock is formed, and almost all streams within the membran
e process are recycled with little discharged as effluent.