We have grown GaInAs:C by low pressure organometallic vapor phase epit
axy and observed that the hole concentration of such layers decreases
upon growth of cap layers such as heterojunction bipolar transistor em
itter layers. Two mechanisms were found to play a role: one is H repas
sivation of the C-As accepters, the other a non-II related decrease in
the concentration of C-As accepters due to C changing site or to the
formation of complexes involving C-As. Depending on the growth conditi
ons of the cap layers (temperature, flow of group V sources), one or t
he other mechanism prevails.