X-RAY PHOTOELECTRON-SPECTROSCOPY STUDY OF THE POLYPROPYLENE MAGNESIUMINTERFACE AFTER INSITU PLASMA AND ION TREATMENT - STICKING, BONDING, AND FILM GROWTH
S. Nowak et al., X-RAY PHOTOELECTRON-SPECTROSCOPY STUDY OF THE POLYPROPYLENE MAGNESIUMINTERFACE AFTER INSITU PLASMA AND ION TREATMENT - STICKING, BONDING, AND FILM GROWTH, Journal of vacuum science & technology. A. Vacuum, surfaces, and films, 11(3), 1993, pp. 481-489
A study on a model system for polymer-metal interface formation after
surface treatment is presented. We discuss a comparative x-ray photoel
ectron spectroscopy analysis of in situ plasma and ion-treated polypro
pylene surfaces with an evaporated magnesium overlayer. The different
surface treatments are found to enhance the sticking probability of th
e metal vapor on the polymer surface considerably. Depending on the ki
nd of surface treatment, different types of bonding of the Mg with the
polymer are observed. The analysis of the excited plasmons is used to
gain information about the interface formation. The experimental resu
lts suggest an island growth mode of the Mg.