Gc. Stutzin et al., DEPOSITION RATES IN DIRECT-CURRENT DIODE SPUTTERING, Journal of vacuum science & technology. A. Vacuum, surfaces, and films, 11(3), 1993, pp. 647-656
A physical model for anode deposition rates in parallel-plate, dc-diod
e sputtering is presented and tested. The deposition rate has been mea
sured as a function of the discharge voltage, the anode-cathode gap an
d the pressure, using silicon or molybdenum cathodes with argon. Depos
ition rates as high as 23 angstrom/s were obtained using 3 kV, and it
is shown that deposition efficiency is similar to that obtained with m
agnetrons. The deposition rate varies inversely with anode-cathode gap
at constant pressure and voltage and almost linearly with power densi
ty for discharge voltages above a threshold which depends on the catho
de material. These observations are explained by the model, which can
be used to estimate the deposition rates for any cathode material and
gas for which the ion sputtering yields are known. Potential advantage
s and complications of dc diode sputtering for thin film deposition ar
e discussed, and optimum conditions for high, uniform deposition rates
are described.