Accurate measurement of the internal quantum yield of photoluminescenc
e is difficult since only a small fraction of the emitted light is col
lected in a luminescence experiment. We propose a novel and alternativ
e method to measure the photoluminescence quantum yield. This method i
s suitable for any material grown on top of another material with a lo
wer band gap. We use a GaAs/AlAs superlattice on a GaAs layer. The int
ensity of luminescence emitted by the GaAs layer when it is directly e
xcited (excitation energy above GaAs band gap, but below the SL band g
ap) is compared to the intensity of luminescence emitted when it is in
directly excited by luminescence light from the superlattice. In the f
irst approximation the internal quantum yield of the superlattice phot
oluminescence is obtained from the ratio of the two luminescence inten
sities. This simple method leads to a slight underestimation of the qu
antum yield, whereas usual and more complicated methods using the exte
rnal quantum efficiency may lead to a large overestimation in the case
of high quantum efficiency and photon recycling effects.