Sy. Reddy et al., TEMPERING METHOD FOR CHOCOLATE CONTAINING MILK-FAT FRACTIONS, Journal of the American Oil Chemists' Society, 73(6), 1996, pp. 723-727
Anhydrous milk fat (AMF) was fractionated by a two-stage dry fractiona
tion process to produce three fractions-high-(HMF), middle-(MMF), and
low-melting (LMF). The effect of replacing 12.2-40% by weight of cocoa
butter with these fractions on the tempering profile of milk chocolat
e was studied. Degree of temper was evaluated by differential scanning
calorimetry, and expressed as the ratio of enthalpies of melting for
higher-stability polymorphs to those of lesser stability. The degree o
f temper was dependent on the crystallization time and temperature, an
d the type and quantity of milk-fat fraction in the formulation. Choco
lates containing AMF or its fractions in concentrations of up to 20 wt
% (total fat basis) were tempered after a conventional thermocycling t
empering process (50 degrees C/30 min, 27.7 degrees C/4 min, 31 degree
s C/2 min) to obtain products with good contraction and mold release p
roperties. For those milk chocolate formulations that did not temper b
y the conventional method and resulted in poor contraction and mold re
lease, a new tempering protocol was developed. Lower crystallization t
emperatures and/or longer holding times were required at concentration
s of AMF, MMF, or LMF above 20%. Chocolate containing HMF required sli
ghtly higher crystallization temperatures because of high viscosity. C
hocolates containing up to 35% HMF and up to 40% of the total weight o
f fat in the chocolate of AMF, MMF, and LMF were successfully tempered
by adjusting crystallization time and temperature.