K. Hiruma et al., SELF-ORGANIZED GROWTH OF GAAS INAS HETEROSTRUCTURE NANOCYLINDERS BY ORGANOMETALLIC VAPOR-PHASE EPITAXY/, Journal of crystal growth, 163(3), 1996, pp. 226-231
Free-standing GaAs/InAs heterostructure wires as thin as 20 nm and as
long as 1 mu m have been formed by vapor-liquid-solid (VLS) growth dur
ing organometallic vapor phase epitaxy. The grown wires were analyzed
by transmission electron microscopy, which revealed that the crystal s
tructure of the GaAs portion coincides with that of zincblende, and th
e InAs portion coincides with that of wurtzite. The atomic composition
along the heterojunction was also measured by energy dispersive X-ray
analysis. The composition changes within a width of 5 nm at the heter
ojunction interface. The InAs/GaAs wires show a photoluminescence peak
around 1.5 eV at 14 K, which indicates significant improvement in cry
stal quality over conventional GaAs/InAs layer structures.