Sm. Gorbatkin et al., CU METALLIZATION USING A PERMANENT-MAGNET ELECTRON-CYCLOTRON-RESONANCE MICROWAVE PLASMA SPUTTERING HYBRID SYSTEM/, Journal of vacuum science & technology. B, Microelectronics and nanometer structures processing, measurement and phenomena, 14(3), 1996, pp. 1853-1859
A permanent magnet electron cyclotron resonance microwave plasma sourc
e has been coupled to a copper sputter target to produce ionized coppe
r fluxes for submicron integrated circuit metallization. A custom laun
cher assembly allows the use of microwave powers up to 5 kW in a metal
deposition environment to produce plasma densities >10(12) cm(-3), we
ll above the cutoff density at 2.45 GHz of similar to 1x10(11) cm(-3).
Six hundred nm, 1.1:1 aspect ratio features have been filled with cop
per, and 250 nm, 6:1 aspect ratio features have been successfully line
d. Copper ionization fractions for the conditions used for lining and
filling, determined by a combination of Langmuir probe measurements an
d optical emission spectroscopy, are between 10% and 35%. (C) 1996 Ame
rican Vacuum Society.