Cy. Yue et al., SYNTHESIS AND CHARACTERIZATION OF CLEAVABLE SURFACTANTS DERIVED FROM POLY(ETHYLENE GLYCOL) MONOMETHYL ETHER, Journal of the American Oil Chemists' Society, 73(7), 1996, pp. 841-845
A series of noncyclic acetal-linked cleavable surfactants were simply
prepared by condensation of aldehydes with poly(ethylene glycol) monom
ethyl ethers. All of the products were characterized by H-1 nuclear ma
gnetic resonance. Their hydrophile-lipophile balance, surface tension,
cloud point, critical micelle concentration, and foam height were det
ermined. Hydrolysis kinetic studies, followed by gas chromatography, s
howed that they had higher hydrolytic reactivity in acidic solution th
an cyclic acetal-linked cleavable surfactants.