Jc. Lin et al., EFFECTS OF SUBSTRATE BIAS ON CRYSTAL-STRUCTURES AND MAGNETIC-PROPERTIES OF COCRTA CR THIN-FILMS/, Materials chemistry and physics, 45(2), 1996, pp. 151-154
Effects of negative d.c. substrate bias on the film properties of CoCr
Ta/Cr magnetic recording media have been investigated. When the substr
ate bias was increased from zero to -250 V, the Ta content was found t
o increase from 3.9 to 15.0 at. %, whereas the Cr content decreased an
d the deposition rate was reduced. X-ray diffraction (XRD) analysis re
vealed the replicate growth of Co (<11(2)over bar 0>) on the Cr (002)
plane. The peak shift and line broadening of Co (<11(2)over bar 0>) di
ffraction are attributed to the compositional change and presence of r
esidual stress in the deposited film. The occurrence of maximum coerci
vity at -150 V bias is correlated to the formation of structural defec
ts. However, too high a bias (-250 V) induces formation of an excessiv
e amount of weak magnetic phase, which causes the magnetic properties
to deteriorate. The enhancement of the coercivity due to substrate bia
s is primarily governed by hindrance of domain wall motion by structur
e defects and/or residual stress.