We have examined new etching methods using vacuum ultraviolet (VUV) li
ght for application to fabrication of semiconductor devices. We have s
uccessfully carried out highly selective and highly anisotropic etchin
g of silicon dioxide using anhydrous HF as an etching gas. We also obt
ained fine 0.1 mu m Si patterns using photo-ionized CF3 + ion etching.
We carried out the low-temperature removal of native-oxide on Si(100)
for very low-temperature homoepitaxy. We have explained the character
istics of VUV light-induced surface reactions on semiconductor materia
l.