KINETICS AND MECHANISM OF REACTION BETWEEN LN(2)O(3) (LN=ND,EU,YB), CUO, AND BACO3 DURING SYNTHESIS OF LNBA(2)CU(3)O(X) AND YB2BACUO5

Authors
SOLOVEVA EN KRZHIZHANOVSKAYA VA GLUSHKOVA VB DORONINA LA
Citation
En. Soloveva et al., KINETICS AND MECHANISM OF REACTION BETWEEN LN(2)O(3) (LN=ND,EU,YB), CUO, AND BACO3 DURING SYNTHESIS OF LNBA(2)CU(3)O(X) AND YB2BACUO5, Inorganic materials, 32(8), 1996, pp. 872-876
Citations number
13
Categorie Soggetti
Material Science
Journal title
Inorganic materials → ACNP
ISSN journal
00201685
Volume
32
Issue
8
Year of publication
1996
Pages
872 - 876
Database
ISI
SICI code
0020-1685(1996)32:8<872:KAMORB>2.0.ZU;2-C
Abstract
DTA, TGA, XRD, and coulometric titration were used to study the kineti cs of reactions between BaCO3, Ln(2)O(3) (Ln = Nd, Eu, Yb), and CuO an d the sequence of chemical transformations during synthesis of LnBa(2) Cu(3)O(x) and Yb2BaCuO5 at temperatures 850-950 degrees C. The conditi ons necessary for synthesis of single-phase products were identified.