T. Matsuoka et al., HOT-CARRIER-INDUCED DEGRADATION OF N2O-OXYNITRIDED GATE OXIDE NMOSFETS, I.E.E.E. transactions on electron devices, 43(9), 1996, pp. 1364-1373
Measurement of long term electrical characteristics of N2O-oxynitrided
gate oxide NMOSFET's revealed that the role of nitrogen-rich layer as
a blocking barrier for molecular hydrogen diffusion plays a dominant
role in the reduced device degradation. A two-step model was proposed,
in which the release of hydrogen species and their reaction with the
trivalent silicon atoms are main factors for hot-carrier-induced-degra
dation. Hot carrier immunity of the NMOSFET's was also found to origin
ate partially from tile small increase of both the effective barrier h
eight for electron injection and the interface trap creation energy du
e to negative charged nitrogen-rich layer.