Jw. Lee et al., ETCHING PROCESSES FOR FABRICATION OF GAN INGAN/ALN MICRODISK LASER STRUCTURES/, Journal of vacuum science & technology. B, Microelectronics and nanometer structures processing, measurement and phenomena, 14(6), 1996, pp. 3637-3640
Several new wet and dry etch processes required for fabrication of mic
rodisk lasers in the III nitrides have been developed. ICl/Ar electron
cyclotron resonance plasmas produce etch rates of 1.3 mu m/ min for G
aN and 1.15 mu m/min for InN at 1000 W microwave power and 250 W Of rf
power. These rates are substantially faster than previously investiga
ted Cl-2/Ar or CH4/H-2 plasma chemistries. Selectivities of 5-6 over A
lN are obtained for these materials. Wet chemical etching of AlN and I
nxAl1-xN in KOH-based solutions was found to be a strong function of e
tch temperature and material quality. The activation energy for these
materials was in the range 2-6 kcal/mol, typical of diffusion-controll
ed processes. The KOH solutions did not etch GaN or InN at temperature
as high as 80 degrees C. (C) 1996 American Vacuum Society.